@article{Li2024, 
author = {Mu-Qing Li and Yulin Cao and Lei Qin and Hua Cheng and Weimin Yang and Zhouguang Lu},
title = {Layered coordination polymer with two-dimensional covalent bismuth-organic networks: Semiconductor and lithium ion storage},
year = {2024},
journal = {Nano Research},
volume = {17},
number = {3},
pages = {2181-2185},
keywords = {semiconductor, bismuth, lithium ion storage, layer coordination polymer (CP)},
url = {https://www.sciopen.com/article/10.1007/s12274-023-6367-6},
doi = {10.1007/s12274-023-6367-6},
abstract = {Single crystals of a bismuth-based coordination polymer (CP) with carboxyl-thiol ligands, [Bi(C8H2O4S2)(C2H8N)]n (Bi-DSBDC-DMA, DMBDC = 2,5-disulfur-1,4-dicarboxylate, DMA = dimethylamine), have been successfully synthesized. X-ray diffraction analysis reveals that Bi-DSBDC-DMA possesses a layered structure, with two-dimensional (2D) Bi-DSBDC networks alternating with layers composed of dimethylamine ions. This material demonstrates semiconducting properties, featuring an optical bandgap of 2.2 eV and an electrical conductivity of 2 × 10−8 S/cm. Furthermore, electrodes based on this material exhibit a capacity of 250 mAh/g after 200 cycles for lithium-ion storage.}
}