TY  - JOUR
AU  - Huang, Chengyu
AU  - Xia, Zhonghong
AU  - Wang, Jing
AU  - Zhang, Jing
AU  - Zhao, Chenfei
AU  - Zou, Xingli
AU  - Mu, Shichun
AU  - Zhang, Jiujun
AU  - Lu, Xionggang
AU  - Fan, Hong Jin
AU  - Huo, Shengjuan
AU  - Zhao, Yufeng
PY  - 2024
TI  - Highly efficient and stable electrocatalyst for hydrogen evolution by molybdenum doped Ni-Co phosphide nanoneedles at high current density
JO  - Nano Research
SN  - 1998-0124
SP  - 1066
EP  - 1074
VL  - 17
IS  - 3
AB  - There is an increasingly urgent need to develop cost-effective electrocatalysts with high catalytic activity and stability as alternatives to the traditional Pt/C in catalysts in water electrolysis. In this study, microspheres composed of Mo-doped NiCoP nanoneedles supported on nickel foam were prepared to address this challenge. The results show that the nanoneedles provide sufficient active sites for efficient electron transfer; the small-sized effect and the micro-scale roughness enhance the entry of reactants and the release of hydrogen bubbles; the Mo doping effectively improves the electrocatalytic performance of NiCoP in alkaline media. The catalyst exhibits low hydrogen evolution overpotentials of 38.5 and 217.5 mV at a current density of 10 mA·cm−2 and high current density of 500 mA·cm−2, respectively, and only 1.978 V is required to achieve a current density of 1000 mA·cm−2 for overall water splitting. Density functional theory (DFT) calculations show that the improved hydrogen evolution performance can be explained as a result of the Mo doping, which serves to reduce the interaction between NiCoP and intermediates, optimize the Gibbs free energy of hydrogen adsorption ( ΔG*H), and accelerate the desorption rate of  *OH. This study provides a promising solution to the ongoing challenge of designing efficient electrocatalysts for high-current-density hydrogen production.
UR  - https://doi.org/10.1007/s12274-023-5892-7
DO  - 10.1007/s12274-023-5892-7