@article{Li2023, 
author = {Huanran Li and Su You and Yongqiang Yu and Lin Ma and Li Zhang and Qing Yang},
title = {Ga/GaSb nanostructures: Solution-phase growth for high-performance infrared photodetection},
year = {2023},
journal = {Nano Research},
volume = {16},
number = {2},
pages = {3304-3311},
keywords = {Ga/GaSb nanostructure, metal-semiconductor heterojunction, narrow bandgap semiconductor, solution–liquid–solid (SLS) growth model, GaSb/Si heterojunction photodetector, hybrid nanostructured photodetector, infrared photodetection},
url = {https://www.sciopen.com/article/10.1007/s12274-022-4931-0},
doi = {10.1007/s12274-022-4931-0},
abstract = {Gallium antimonide (GaSb)-based nanostructures have been reported via various vapor-phase synthetic routes while there is not a report on the growth of GaSb nanostructures via a complete one-step solution-phase synthetic strategy. Herein we report the design and synthesis of tadpole-like Ga/GaSb nanostructures by a one-step solution-phase synthetic route typically from the precursors of commercial triphenyl antimony (Sb(Ph)3) and trimethylaminogallium (Ga(NMe2)3) at 260 °C in 1-octadecene. The GaSb nanocrystals are grown based on a solution–liquid–solid (SLS) mechanism with zinc blende phase, and their size and shape can be controlled in the procedures via manipulating the reaction conditions. Meanwhile, the tadpole-like Ga/GaSb nanostructures can be applied for the fabrication of a GaSb/Si nanostructured heterojunction-like photodetector over silicon wafer, which demonstrates excellent photoresponse and detection performances from wavelength of 405 to 1,064 nm with high photoresponding rate. Typically, the photodetector exhibits a high responsivity of 18.9 A·W−1, a superior detectivity of 1.1 × 1013 Jones, and an ultrafast response speed of 44 ns. The present work provides a new strategy to group III–V antimonide-based semiconducting nanostructures that are capable for the fabrication of photodetector with broadband, high-detectivity, and high-speed photodetecting performances.}
}