@article{Chen2022, 
author = {Weiming Chen and Peipei Li and Jia Yu and Peixin Cui and Xiaohu Yu and Weiguo Song and Changyan Cao},
title = {In-situ doping nickel single atoms in two-dimensional MXenes analogue support for room temperature NO2 sensing},
year = {2022},
journal = {Nano Research},
volume = {15},
number = {10},
pages = {9544-9553},
keywords = {sensing, MXenes, molten salt, single atom, NO2},
url = {https://www.sciopen.com/article/10.1007/s12274-022-4904-3},
doi = {10.1007/s12274-022-4904-3},
abstract = {MXenes are promising supports for anchoring metal single atoms due to their versatile composition, well-defined nanostructures, and suitable conductivity. However, metal single atoms are usually coordinated with surface terminal groups (-O, -OH, -Cl, etc.) of MXenes via conventional wet-impregnation, resulting in limited electronic structure modification. Through a NiCl2 molten salt etching method, we observed that Ni single atoms could be in-situ doped in the lattice of MXenes analogue TiC0.5N0.5 support (denoted as Ni1/TiC0.5N0.5), resulting in much larger charge transfer from Ni atoms to adjacent Ti atoms, and thus increasing the electronic density of these Ti atoms. When used for NO2 sensing, Ni1/TiC0.5N0.5 exhibited excellent response sensitivity (ultra-low limit of detection ~ 10 ppb), selectivity, and good stability at room temperature. This study provides an effective strategy for producing MXenes analogue supported metal single atoms for potential application in gas sensing.}
}