@article{Lu2023, 
author = {Zhili Lu and Chaohui Li and Hongwei Lai and Xinming Zhou and Chunfeng Wang and Xianhu Liu and Fei Guo and Caofeng Pan},
title = {Mixed 2D-Dion–Jacobson/3D Sn-Pb alloyed perovskites for efficient photovoltaic solar devices},
year = {2023},
journal = {Nano Research},
volume = {16},
number = {2},
pages = {3142-3148},
keywords = {solar cells, Sn-Pb perovskite, narrow bandgap, Dion–Jacobson perovskite, two-dimensional (2D)/three-dimensional (3D)},
url = {https://www.sciopen.com/article/10.1007/s12274-022-4894-1},
doi = {10.1007/s12274-022-4894-1},
abstract = {Tin-lead (Sn-Pb) alloyed perovskites with tunable bandgaps hold great potential for constructing highly efficient single-junction and tandem photovoltaic devices. However, the efficiency and stability of Sn-Pb perovskite solar cells (PSCs) are greatly hampered by severe nonradiative recombination due to the easy oxidation of Sn(II). In this work, we report the construction of mixed dimensional two-dimensional (2D) Dion–Jacobson (DJ) and three-dimensional (3D) perovskites to improve the efficiency and stability of Sn-Pb alloyed PSCs. Introducing a small amount of 1,4-butanediammonium diiodide as spacer cations of DJ perovskites into precursor, the prepared mixed dimensional Sn-Pb alloyed perovskites exhibit reduced trap-state density due to the passivation of 2D DJ perovskites. As a result, nonradiative charge recombination is greatly suppressed. The prepared Sn-Pb alloyed PSCs based on 2D-DJ/3D heterojunction deliver a power conversion efficiency of 19.02% with an impressive fill factor of 80%. As well, improved device stability is realized due to the presence of DJ perovskites which serves as a protection barrier against oxidation and water invasion.}
}