@article{JI2022, 
author = {Xiaoyu JI and Yiruo ZHANG and Mengxue CAO and Quanchao GU and Honglei WANG and Jinshan YU and Zi-Hao GUO and Xingui ZHOU},
title = {Advanced inorganic/polymer hybrid electrolytes for all-solid-state lithium batteries},
year = {2022},
journal = {Journal of Advanced Ceramics},
volume = {11},
number = {6},
pages = {835-861},
keywords = {solid-state electrolytes (SSEs), hybrid electrolytes, energy density, electrical energy storage (EES), lithium batteries},
url = {https://www.sciopen.com/article/10.1007/s40145-022-0580-8},
doi = {10.1007/s40145-022-0580-8},
abstract = {Solid-state batteries have become a frontrunner in humankind’s pursuit of safe and stable energy storage systems with high energy and power density. Electrolyte materials, currently, seem to be the Achilles’ heel of solid-state batteries due to the slow kinetics and poor interfacial wetting. Combining the merits of solid inorganic electrolytes (SIEs) and solid polymer electrolytes (SPEs), inorganic/polymer hybrid electrolytes (IPHEs) integrate improved ionic conductivity, great interfacial compatibility, wide electrochemical stability window, and high mechanical toughness and flexibility in one material, having become a sought-after pathway to high-performance all-solid-state lithium batteries. Herein, we present a comprehensive overview of recent progress in IPHEs, including the awareness of ion migration fundamentals, advanced architectural design for better electrochemical performance, and a perspective on unconquered challenges and potential research directions. This review is expected to provide a guidance for designing IPHEs for next-generation lithium batteries, with special emphasis on developing high-voltage-tolerance polymer electrolytes to enable higher energy density and three-dimensional (3D) continuous ion transport highways to achieve faster charging and discharging.}
}