@article{Lawan Adam2022, 
author = {Mukhtar Lawan Adam and Hongen Zhu and Zhanfeng Liu and Shengtao Cui and Pengjun Zhang and Yi Liu and Guobin Zhang and Xiaojun Wu and Zhe Sun and Li Song},
title = {Charge density wave phase suppression in 1T-TiSe2 through Sn intercalation},
year = {2022},
journal = {Nano Research},
volume = {15},
number = {3},
pages = {2643-2649},
keywords = {first-principles, intercalation, charge density wave, angle-resolved photoemission spectroscopy (ARPES), charge doping, single-crystals},
url = {https://www.sciopen.com/article/10.1007/s12274-021-3859-0},
doi = {10.1007/s12274-021-3859-0},
abstract = {Taking advantage of the unique layered structure of TiSe2, the intrinsic electronic properties of two-dimensional materials can easily be tuned via heteroatomic engineering. Herein, we show that the charge density wave (CDW) phase in 1T-TiSe2 single-crystals can be gradually suppressed through Sn atoms intercalation. Using angle-resolved photoemission spectroscopy (ARPES) and temperature-dependent resistivity measurements, this work reveals that Sn atoms can induce charge doping and modulate the intrinsic electronic properties in the host 1T-TiSe2. Notably, our temperature-dependent ARPES results highlight the role exciton-phonon interaction and the Jahn-Teller mechanism through the formation of backfolded bands and exhibition of a downward Se shift of 4p valence band in the formation of CDW in this material.}
}