@article{Shi2017, 
author = {Gang Shi and Xin Zhang and Jianhua Li and Haiyan Zhu and Ying Li and Liping Zhang and Caihua Ni and Lifeng Chi},
title = {Fabrication of 3D biomimetic composite coating with broadband antireflection, superhydrophilicity, and double p-n heterojunctions},
year = {2017},
journal = {Nano Research},
volume = {10},
number = {7},
pages = {2377-2385},
keywords = {biomimetic composite coating, broadband antireflection, superhydrophilicity, double p-n heterojunctions},
url = {https://www.sciopen.com/article/10.1007/s12274-017-1434-5},
doi = {10.1007/s12274-017-1434-5},
abstract = {The traditional single material with two-dimensional (2D) biomimetic moth-eye structures is limited by its narrowband antireflection and single functional capability. To overcome these disadvantages, we exploited wet etching and hydrothermal synthesis coupled with chemical oxidation for fabricating a three- dimensional (3D) biomimetic moth-eye coating with ternary materials (polypyrrole nanoparticles, TiO2 nanorods, and Si micropyramids, i.e., PPy/TiO2/Si-p). This coating reduced the reflectivity to < 4% at wavelengths ranging from 200 to 2, 300 nm and exhibited remarkable superhydrophilicity with a low water contact angle of 1.8°. Moreover, the composite coating had double p-n heterojunctions, allowing the high-efficiency separation of photogenerated carriers. The photocurrent density of PPy/TiO2/Si-p was more than three times higher than that of TiO2/Si-p at a positive potential of 1.5 V. The proposed method provides a means to enhance solar energy conversion.}
}