@article{Wang2022, 
author = {Haiqing Wang},
title = {Nanostructure@metal-organic frameworks (MOFs) for catalytic carbon dioxide (CO2) conversion in photocatalysis, electrocatalysis, and thermal catalysis},
year = {2022},
journal = {Nano Research},
volume = {15},
number = {4},
pages = {2834-2854},
keywords = {nanostructure@MOFs, CO2 reduction, CO2 photocatalysis, CO2 electrocatalysis, CO2 thermal catalysis},
url = {https://www.sciopen.com/article/10.1007/s12274-021-3984-9},
doi = {10.1007/s12274-021-3984-9},
abstract = {The catalytic conversion of carbon dioxide (CO2) into high value-added chemicals is of great significance to address the pressing carbon cycle issues. Reticular chemistry of metal-organic frameworks (MOFs)-based materials exhibits great potential and effectiveness to face CO2 challenge from capture to conversion. To date, the integrated nanocomposites of nanostructure and MOF have emerged as a powerful heterogeneous catalysts featured with multifold advantages including synergistic effects between the two interfaces, confinement effect of meso- and micropores, tandem reaction triggered by multiple active sites, high stability and dispersion, and so on. Given burgeoning carbon cycle and nanostructure@MOFs, this review highlights some of important advancements to provide a full understanding on the synthesis and design of nanostructure@MOFs composites to facilitate carbon cycle through CO2 photocatalytic, electrocatalytic, and thermal conversion. Afterward, the catalytic applications of some representative nanostructure@MOFs composites are categorized, in which the origin of activity or structure-activity relationship is summarized. Finally, the opportunities and challenges are proposed for inspiring the future development of nanostructure@MOFs composites for carbon cycle.}
}