@article{Qiu2014, 
author = {Yongcai Qiu and Wanfei Li and Guizhu Li and Yuan Hou and Lisha Zhou and Hongfei Li and Meinan Liu and Fangmin Ye and Xiaowei Yang and Yuegang Zhang},
title = {Polyaniline-modified cetyltrimethylammonium bromide–graphene oxide–sulfur nanocomposites with enhanced performance for lithium–sulfur batteries},
year = {2014},
journal = {Nano Research},
volume = {7},
number = {9},
pages = {1355-1363},
keywords = {lithium-sulfur batteries, polyaniline, graphene oxide-sulfur, long-term cycling},
url = {https://www.sciopen.com/article/10.1007/s12274-014-0500-5},
doi = {10.1007/s12274-014-0500-5},
abstract = {Conductive polymer coatings can boost the power storage capacity of lithium-sulfur batteries. We report here on the design and preparation-by combining a facile and green chemical deposition method with an oxidative polymerization approach-of polyaniline (PANI)-modified cetyltrimethylammonium bromide (CTAB)-graphene oxide (GO)-sulfur (S) nanocomposites with significantly enhanced performance in lithium-sulfur batteries. Such conductive polymer modified CTAB-GO-S nanocomposites as sulfur cathode materials can deliver high specific discharge capacities and long-term cycling performance, i.e., ~970 mAh·g-1 at 0.2 C and ~715 mAh·g-1 after 300 cycles, ~820 mAh·g-1 at 0.5 C and ~670 mAh·g-1 after 500 cycles, ~770 mAh·g-1 at 1 C and ~570 mAh·g-1 after 500 cycles. The capacity decay was as low as 0.036% per cycle at 0.5 C, and 0.051% per cycle at 1 C. Under the same condition, batteries using PANI-modified CTAB-GO-S as cathodes exhibited higher specific capacity and higher average coulombic efficiency compared with CTAB-decorated GO-S and GO-S nanocomposites. The improved performance can be attributed to the lower charge transfer resistance and the alleviated dissolution of polysulfides in the PANImodified CTAB-GO-S cathodes.}
}