@article{Ren2018, 
author = {Xiang Ren and Dan Wu and Ruixiang Ge and Xu Sun and Hongmin Ma and Tao Yan and Yong Zhang and Bin Du and Qin Wei and Liang Chen},
title = {Self-supported CoMoS4 nanosheet array as an efficient catalyst for hydrogen evolution reaction at neutral pH},
year = {2018},
journal = {Nano Research},
volume = {11},
number = {4},
pages = {2024-2033},
keywords = {density functional theory, hydrogen evolution reaction, CoMoS4 nanosheet array, anion exchange reaction, neutral pH},
url = {https://www.sciopen.com/article/10.1007/s12274-017-1818-6},
doi = {10.1007/s12274-017-1818-6},
abstract = {Development of earth-abundant electrocatalysts, particularly for high-efficiency hydrogen evolution reaction (HER) under benign conditions, is highly desired, but still remains a serious challenge. Herein, we report a high-performance amorphous CoMoS4 nanosheet array on carbon cloth (CoMoS4 NS/CC), prepared by hydrothermal treatment of a Co(OH)F nanosheet array on a carbon cloth (Co(OH)F NS/CC) in (NH4)2MoS4 solution. As a three-dimensional HER electrode, CoMoS4 NS/CC exhibits remarkable activity in 1.0 M phosphate buffer saline (pH 7), only requiring an overpotential of 183 mV to drive a geometrical current density of 10 mA·cm–2. This overpotential is 140 mV lower than that for Co(OH)F NS/CC. Notably, this electrode also shows outstanding electrochemical durability and nearly 100% Faradaic efficiency. Density functional theory calculations suggest that CoMoS4 has a more favorable hydrogen adsorption free energy than Co(OH)F.}
}