@article{Huang2021, 
author = {Xiaoqin Huang and Deli Li and Haijian Huang and Xiao Jiang and Zeheng Yang and Weixin Zhang},
title = {Fast and highly reversible Na+ intercalation/extraction in Zn/Mg dual-doped P2-Na0.67MnO2 cathode material for high-performance Na-ion batteries},
year = {2021},
journal = {Nano Research},
volume = {14},
number = {10},
pages = {3531-3537},
keywords = {Na-ion batteries, cathode materials, co-doping, Na-ion diffusion, structural stability},
url = {https://www.sciopen.com/article/10.1007/s12274-021-3715-2},
doi = {10.1007/s12274-021-3715-2},
abstract = {P2-type layered Na0.67MnO2 has been considered to be a promising candidate cathode material for sodium ion batteries. Nevertheless, the undesired phase transitions during operation and the large Na+ radius induced sluggish ion diffusion remain the stumbling blocks to realize its high performance. Herein, we propose a Zn/Mg co-doping strategy, which is proved to have bifunctional effects. First, relative to the pristine P2-Na0.67MnO2 and the single-ion (Zn/Mg) doped samples, the Zn/Mg dual-doped P2-Na0.67MnO2 demonstrates a lower Mn3+/Mn4+ ratio and a higher lattice O content, which facilitate the structural stability of the cathode material. More intriguingly, the Zn/Mg co-doping gives rise to enlarged interplanar spacing, which provides spacious ion diffusion channels for fast Na+ intercalation/extraction. As a result, the Zn/Mg dual-doped sample exhibits a high Na+ diffusion coefficient and a solid-solution reaction during charge/discharge, with a cell volume change determined to be only 0.55%. Taking advantages of the above favorable features, the Zn/Mg dual-doped P2-Na0.67MnO2 demonstrates a high rate performance with 67.2 mAhdg-1 delivered at 10 C and a decent cycling stability with a capacity retention of 93.8% achieved at 1 C after 100 cycles. This work introduces the Zn/Mg co-doping strategy to simultaneously improve the cycling stability and rate capability of P2-Na0.67MnO2, which may offer a promising avenue for further performance enhancement of the layered Na-ion batteries cathode materials.}
}