@article{Zhao2021, 
author = {Xiaojuan Zhao and Houzhao Wan and Pei Liang and Nengze Wang and Cong Wang and Yi Gan and Xu Chen and Qiuyang Tan and Xiang Liu and Jun Zhang and Yi Wang and Hanbin Wang and Hao Wang},
title = {Favorable anion adsorption/desorption of high rate NiSe2 nanosheets/hollow mesoporous carbon for battery-supercapacitor hybrid devices},
year = {2021},
journal = {Nano Research},
volume = {14},
number = {8},
pages = {2574-2583},
keywords = {core-shell structure, supercapacitor, nickel selenide, mesoporous carbon, high rate},
url = {https://www.sciopen.com/article/10.1007/s12274-020-3257-z},
doi = {10.1007/s12274-020-3257-z},
abstract = {High-rate battery-type cathode materials have attracted wide attention for advanced battery-supercapacitor hybrid (BSH) devices. Herein, a core-shell structure of the hollow mesoporous carbon spheres (HMCS) supported NiSe2 nanosheets (HMCS/NiSe2) is constructed through two-step reactions. The HMCS/NiSe2 shows a max specific capacity of 1,153.5 C·g-1 at the current density of 1 A·g-1, and can remain at 774.5 C·g-1 even at 40 A·g-1 (the retention rate as high as 67.1%) and then the HMCS/NiSe2 electrode can keep 80.5% specific capacity after 5,000 cycles at a current density of 10 A·g-1. Moreover, the density functional theory (DFT) calculation confirmed that the introduction HMCS into NiSe2 made adsorption/desorption of OH- easier, which can achieve higher rate capability. The HMCS/NiSe2//6 M KOH//HMCS hybrid device has energy density of 47.15 Wh·kg-1 and power density of 801.8 W·kg-1. This work provides a feasible electrode material with a high rate and its preparation method for high energy density and power density energy storage devices.}
}