@article{Li2016, 
author = {Liuyi Li and Caiyan Cui and Wenyue Su and Yangxin Wang and Ruihu Wang},
title = {Hollow click-based porous organic polymers for heterogenization of [Ru(bpy)3]2+ through electrostatic interactions},
year = {2016},
journal = {Nano Research},
volume = {9},
number = {3},
pages = {779-786},
keywords = {porous organic polymers, hollow, heterogenization, cationic metal complex, catalysis},
url = {https://www.sciopen.com/article/10.1007/s12274-015-0957-x},
doi = {10.1007/s12274-015-0957-x},
abstract = {A facile approach for the heterogenization of transition metal catalysts using non-covalent interactions in hollow click-based porous organic polymers (H-CPPs) is presented. A catalytically active cationic species, [Ru(bpy)3]2+ (bpy = 2, 2'-bipyridyl), was immobilized in H-CPPs via electrostatic interactions. The intrinsic properties of [Ru(bpy)3]2+ were well retained. The resulting Rucontaining hollow polymers exhibited excellent catalytic activity, enhanced stability, and good recyclability when used for the oxidative hydroxylation of 4-methoxyphenylboronic acid to 4-methoxyphenol under visible-light irradiation. The attractive catalytic performance mainly resulted from efficient mass transfer and the maintenance of the chemical properties of the cationic Ru complex in the H-CPPs.}
}