@article{Song2019, 
author = {Meijia Song and Jiazheng Niu and Kuibo Yin and Hui Gao and Chi Zhang and Wensheng Ma and Fakui Luo and Zhangquan Peng and Zhonghua Zhang},
title = {Self-supporting, eutectic-like, nanoporous biphase bismuth-tin film for high-performance magnesium storage},
year = {2019},
journal = {Nano Research},
volume = {12},
number = {4},
pages = {801-808},
keywords = {hierarchically porous structure, magnesium ion batteries, alloying-type anode, biphase bismuth-tin film, magnetron cosputtering},
url = {https://www.sciopen.com/article/10.1007/s12274-019-2291-1},
doi = {10.1007/s12274-019-2291-1},
abstract = {Magnesium ion batteries are emerging as promising alternatives to lithium ion batteries because of their advantages including high energy density, dendrite-free features and low cost. Nevertheless, one of the major challenges for magnesium ion batteries is the kinetically sluggish magnesium insertion/extraction and diffusion in electrode materials. Aiming at this issue, biphase eutectic-like bismuth-tin film is designed herein to construct a self-supporting anode with interdigitated phase distribution and hierarchically porous structure, and further fabricated by a facile one-step magnetron cosputtering route. As benchmarked with single-phase bismuth or tin film, the biphase bismuth-tin film delivers high specific capacity (538 mAh/g at 50 mA/g), excellent rate performance (417 mAh/g at 1, 000 mA/g) and good cycling stability (233 mAh/g at the 200th cycle). The superior magnesium storage performance of the sputtered bismuth-tin film could be attributed to the synergetic effect of the interdigitated bismuth/tin phase distribution, hierarchically porous structure and biphase buffering matrices, which could increase ionic transport channels, shorten diffusion lengths and reduce total volume changes.}
}