@article{Si2021, 
author = {Yanan Si and Xiang He and Jie Jiang and Zhiming Duan and Wenjing Wang and Daqiang Yuan},
title = {Highly effective H2/D2 separation in a stable Cu-based metal-organic framework},
year = {2021},
journal = {Nano Research},
volume = {14},
number = {2},
pages = {518-525},
keywords = {metal-organic framework (MOFs), hydrogen isotope, separation, breakthrough experiments},
url = {https://www.sciopen.com/article/10.1007/s12274-019-2571-9},
doi = {10.1007/s12274-019-2571-9},
abstract = {A three-dimensional copper metal-organic framework with the rare chabazite (CHA) topology namely FJI-Y11 has been constructed with flexibly carboxylic ligand 5,5'-[(1,4-phenylenebis(methylene))bis(oxy)]diisophthalic acid (H4L). FJI-Y11 exhibits high water stability with the pH range from 2 to 12 at temperature as high as 373 K. Importantly, FJI-Y11 also shows high efficiency of hydrogen isotope separation using dynamic column breakthrough experiments under atmospheric pressure at 77 K. Attributed to its excellent structural stability, FJI-Y11 possesses good regenerated performance and maintains high separation efficiency after three cycles of breakthrough experiments.}
}