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Research Article | Open Access

Synthesis, Characterization and Applications of (E)-3-((5-bromo-2-hydroxy-3-methoxycyclohexa-1,3-dienyl) methyleneamino)-6-(hydroxymethyl)-tetrahydro-2H-pyran-2,4,5-triol

Solomon Tadesse1, Yelda Bingöl Alpaslan2, Mustafa Yıldız3,4( ), Hüseyin Ünver5, Kadir Aslan1( )
Morgan State University, Department of Chemistry, 1700 East Cold Spring Lane, Baltimore, MD 21251, USA
Department of Biophysics, Faculty of Medicine, Giresun University, Giresun, Turkey
Department of Chemistry, Faculty of Arts and Sciences, Çanakkale Onsekiz Mart University, 17100 Çanakkale, Turkey
Nanoscience and Technology Research and Application Center (NANORAC), Çanakkale Onsekiz Mart University, Çanakkale, Turkey
Department of Physics, Faculty of Science, Ankara University, 06100 Besevler-Ankara, Turkey
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Abstract

We present the synthesis, characterization, biological and sensing applications of a Schiff base, (E)-3-((5-bromo-2-hydroxy-3-methoxycyclohexa-1, 3-dienyl)methyleneamino)-6-(hydroxymethyl)-tetrahydro-2H-pyran-2,4,5-triol. Characterization of the title compound was carried out using theoretical quantum-mechanical calculations and experimental spectroscopic methods. The molecular structure of the title compound was confirmed using NMR and FTIR, which was in good agreement with the structure predicted by the theoretical calculations. The title compound was evaluated for its ability to detect anions in DMSO and on a solid surface and for its antimicrobial activity against several common microorganisms.

Keywords

Schiff baseα-D-GlucosamineDensity functional theoryAnion sensingAntimicrobial activity

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Nano Biomedicine and Engineering
Volume 8 Issue 2,
June 2016
Pages 72-81
DOI: 10.5101/nbe.v8i2.p72-81

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Tadesse S, Alpaslan YB, Yıldız M, et al. Synthesis, Characterization and Applications of (E)-3-((5-bromo-2-hydroxy-3-methoxycyclohexa-1,3-dienyl) methyleneamino)-6-(hydroxymethyl)-tetrahydro-2H-pyran-2,4,5-triol. Nano Biomedicine and Engineering, 2016, 8(2): 72-81. https://doi.org/10.5101/nbe.v8i2.p72-81

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Received: 15 March 2016
Accepted: 10 May 2016
Published: 13 May 2016
© 2016 Solomon Tadesse, Yelda Bingöl Alpaslan, Mustafa Yıldız, Hüseyin Ünver and Kadir Aslan.

This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.