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Polyoxometalates 2022, 1(2): 9140009 https://doi.org/10.26599/POM.2022.9140009
Research Article | Open Access | Issue | Published: 01 November 2022

Multistimuli-responsive circularly polarized luminescent material of achiral Eu-containing polyoxometalates and cellulose nanocrystals

Show Author's Information Rong Wang,  Peiyao Yu,  Junyan Tan,  Yue Zhou,  Jie Zhang ( )
Beijing National Laboratory for Molecular Science, Key Laboratory of Polymer Chemistry and Physics of Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China
Keywords:
stimuli-responsive, polyoxometalates, circularly polarized luminescence, cellulose nanocrystals
Cite this article:
Wang R, Yu P, Tan J, et al. Multistimuli-responsive circularly polarized luminescent material of achiral Eu-containing polyoxometalates and cellulose nanocrystals. Polyoxometalates, 2022, 1(2): 9140009. https://doi.org/10.26599/POM.2022.9140009
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Abstract Full text Electronic supplementary material About this article

The stimuli-responsive circularly polarized luminescence (CPL) material was made using photonic cellulose nanocrystals (CNC) and achiral luminescent Eu-containing polyoxometalates Na9EuW10O36·32H2O (EuW10). The CPL of EuW10 with high dissymmetric factor glum ~ −0.37 was achieved based on the selective reflection property of CNC photonic films. With the increase of polyethylene glycol (PEG) content, the photonic bandgaps (PBG) of CNC/PEG/EuW12 composite films were redshifted, successfully achieving the chirality of EuW10 in various emission bands (5D0→7Fn, n = 1, 2, 3, 4). The CPL materials also showed excellent humidity responsiveness. The glum of the emission band was closely correlated to the PBG of composite films.


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About this article

Multistimuli-responsive circularly polarized luminescent material of achiral Eu-containing polyoxometalates and cellulose nanocrystals

Show Author's information Rong Wang, Peiyao Yu, Junyan Tan, Yue Zhou, Jie Zhang ( )
Beijing National Laboratory for Molecular Science, Key Laboratory of Polymer Chemistry and Physics of Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China

Abstract

The stimuli-responsive circularly polarized luminescence (CPL) material was made using photonic cellulose nanocrystals (CNC) and achiral luminescent Eu-containing polyoxometalates Na9EuW10O36·32H2O (EuW10). The CPL of EuW10 with high dissymmetric factor glum ~ −0.37 was achieved based on the selective reflection property of CNC photonic films. With the increase of polyethylene glycol (PEG) content, the photonic bandgaps (PBG) of CNC/PEG/EuW12 composite films were redshifted, successfully achieving the chirality of EuW10 in various emission bands (5D0→7Fn, n = 1, 2, 3, 4). The CPL materials also showed excellent humidity responsiveness. The glum of the emission band was closely correlated to the PBG of composite films.

Keywords: stimuli-responsive, polyoxometalates, circularly polarized luminescence, cellulose nanocrystals

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Received: 30 July 2022
Revised: 17 September 2022
Accepted: 06 October 2022
Published: 01 November 2022
Issue date: December 2022

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© The Author(s) 2022. Polyoxometalates published by Tsinghua University Press.

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