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Regular Paper | Open Access

Enhanced Electrical Properties of Styrene-grafted Polypropylene Insulation for Bulk Power Transmission HVDC Cables

Hao Yuan1Shixun Hu2( )Yao Zhou2Chao Yuan2Wenbo Song1Qing Shao1Hongwei Shi1Juan Li1Jun Hu2Qi Li2Jinliang He2
SINOPEC Beijing Research Institute of Chemical Industry, Beijing 100013, China
State Key Laboratory of Power Systems, Department of Electrical Engineering, Tsinghua University, Beijing 100084, China
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Abstract

Polypropylene (PP) is considered to be a rather promising material for HVDC cable insulation. Grafting modification has proved to be an effective method on the electrical property improvements of PP. This paper reports on the highly-enhanced electrical properties of styrene-grafted polypropylene (PP-g-St) and their related mechanism. The influence of grafting styrene on crystallization structures, thermal properties and electrical properties of PP-g-St are characterized and analyzed. These results show that PP-g-St exhibits remarkably enhanced DC volume resistivity, suppressed space charge accumulation and improved DC breakdown strengths as compared to PP. Crystallization observation shows PP-g-St has small, imperfect spherulites with indistinct boundaries, which is strongly correlated to enhanced electrical properties. This study provides an effective grafting strategy to design high-performance HVDC cable insulation materials for bulk power transmission systems.

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CSEE Journal of Power and Energy Systems
Pages 361-370
Cite this article:
Yuan H, Hu S, Zhou Y, et al. Enhanced Electrical Properties of Styrene-grafted Polypropylene Insulation for Bulk Power Transmission HVDC Cables. CSEE Journal of Power and Energy Systems, 2024, 10(1): 361-370. https://doi.org/10.17775/CSEEJPES.2021.00850

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Received: 01 February 2021
Revised: 14 April 2021
Accepted: 10 May 2021
Published: 30 December 2021
© 2021 CSEE.

This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/)

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