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Research Article | Open Access

Super-stable permittivity and low dielectric loss of (1-x)Na0.5Bi0.5+yTiO3-xNaTaO3 ceramics within an ultra-wide temperature range

Pengrong Rena( ), Han Zhaoa, Xin Wangb, Yuhui Wana, Zhiyong Liuc, Changbai Longd, Fuxue Yana, Till Frӧmlinge, Gaoyang Zhaoa
Shaanxi Province Key Laboratory for Electrical Materials and Infiltration Technology, School of Materials Science and Engineering, Xi'an University of Technology, Xi'an, 710048, China
Laboratory of Thin Film Techniques and Optical Test, School of Photoelectrical Engineering, Xi'an Technological University, Xi'an, 710032, China
School of Materials Science and Engineering, Nanchang Hangkong University, Nanchang, 330063, China
State Key Laboratory for Mechanical Behavior of Materials, Xi'an Jiaotong University, Xi'an, 710049, China
Institute of Materials Science, Technische Universität Darmstadt, FB Nichtmetallisch-Anorganische Werkstoffe, Alarich-Weiss-Straße 2, D-64287, Darmstadt, Germany

Peer review under responsibility of The Chinese Ceramic Society.

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Graphical Abstract

Abstract

This work designs a new system (1-x)Na0.5Bi0.5+yTiO3-xNaTaO3 with a nonstoichiometric bismuth ratio, which is used as dielectrics of ceramics capacitors. Phase structure evolution of (1-x)Na0.5BiTiO3-xNaTaO3 is characterized using XRD, Raman and TEM. Dielectric and resistant properties of (1-x)Na0.5Bi0.5+yTiO3-xNaTaO3 are investigated with increasing concentration of NaTaO3. With these investigations, the structure and defect chemistry of (1-x)Na0.5Bi0.5+yTiO3-xNaTaO3 are rationalized and their respective impact on capacitor properties are elucidated. The optimized composition 0.8Na0.5Bi0.51TiO3-0.2NaTaO3 possesses an ultra-wide operating temperature range (-92–398 ℃), in which both stable permittivity and low dielectric loss is obtained. Furthermore, the fabrication of multilayer ceramics capacitors (MLCC) based on 0.8Na0.5Bi0.51TiO3-0.2NaTaO3 dielectrics is investigated. With the addition of sintering aids, 0.8Na0.5Bi0.51TiO3-0.2NaTaO3 could be co-fired with Ag at 910 ℃ in air, and the low temperature co-fired ceramic (LTCC) capacitors maintain good temperature stability of permittivity and low dielectric loss in -100–352 ℃. Therefore, our work provides a new route for preparing ultra-wide operating temperature capacitors at low manufacturing costs.

Keywords

Na1/2Bi1/2TiO3PermittivityDielectric lossUltra-wide operating temperature capacitors

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Journal of Materiomics
Volume 9 Issue 3,
May 2023
Pages 482-491
DOI: 10.1016/j.jmat.2022.12.004
Cite this article:
Ren P, Zhao H, Wang X, et al. Super-stable permittivity and low dielectric loss of (1-x)Na0.5Bi0.5+yTiO3-xNaTaO3 ceramics within an ultra-wide temperature range. Journal of Materiomics, 2023, 9(3): 482-491. https://doi.org/10.1016/j.jmat.2022.12.004

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Received: 06 November 2022
Revised: 10 December 2022
Accepted: 11 December 2022
Published: 13 January 2023
© 2023 The Authors.

This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
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