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Short Communication | Open Access

Atomic layer deposition of core-shell structured V2O5@CNT sponge as cathode for potassium ion batteries

Fangliang Yea, Dongwei Lub, Xuchun Guib, Tengrui Wanga, Xiaoying Zhuangc, Wei Luoa( ), Yunhui Huanga( )
Institute of New Energy for Vehicles, School of Materials Science and Engineering, Tongji University, Shanghai, 201804, China
State Key Laboratory of Optoelectronic Materials and Technologies, School of Electronics and Information Technology, Sun Yat-sen University, Guangzhou, 510275, China
Department of Geotechnical Engineering, College of Civil Engineering, Tongji University, Shanghai, 200092, China

Peer review under responsibility of The Chinese Ceramic Society.

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Graphical Abstract

Abstract

Potassium-ion batteries (KIBs) represent one of the most promising alternatives to lithium-ion batteries (LIBs) considering the potential low cost and abundant potassium resource. In this work, we demonstrate a core-shell structured sponge cathode for KIBs, where amorphous V2O5 uniformly coats on carbon nanotube (CNT) sponge via atomic layer deposition (ALD). The V2O5@CNT sponge shows several advantages as cathode: (1) the three-dimensional (3D) conductive network of CNT sponge offers a fast electron transport pathway, (2) the porous nature and high surface area of CNT sponge enables enough access for electrolyte to V2O5, (3) the amorphous structure of V2O5 offers a fast kinetics upon K-ion insertion/deinsertion. The V2O5@CNT sponge cathode delivers a high capacity of 206 mA h/g and moderate cycling and rate performance in common carbonate-based electrolyte system.

Keywords

Potassium ion batteriesAtomic layer depositionAmorphous vanadium oxideCarbon nanotube sponge

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Journal of Materiomics
Volume 5 Issue 3,
September 2019
Pages 344-349
DOI: 10.1016/j.jmat.2018.05.009
Cite this article:
Ye F, Lu D, Gui X, et al. Atomic layer deposition of core-shell structured V2O5@CNT sponge as cathode for potassium ion batteries. Journal of Materiomics, 2019, 5(3): 344-349. https://doi.org/10.1016/j.jmat.2018.05.009

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Received: 26 April 2018
Revised: 20 May 2018
Accepted: 26 May 2018
Published: 28 May 2018
© 2019 The Chinese Ceramic Society. Production and hosting by Elsevier B.V.

This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
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