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In recent years, a new 2D-layered material—black phosphorus (BP)—has been a rising star after the era of graphene owing to its high charge carrier mobility, tunable direct bandgap and unique in-plane anisotropic structure. With the development of the synthesis and modification methods of BP, its extensive applications, e.g., transistors, batteries and optoelectronics have emerged. In order to explore its full potential, research into the tribological properties of BP 2D-layered materials such as lubrication additives and fillers in self-lubricating composite materials would be not only of high scientific value but also of practical significance. In this work, recent advances on the friction and lubrication properties of BP nanosheets made by our group, including the micro-friction properties, the lubrication properties of BP nanosheets as water-based and oil-based lubrication additives, and the friction and wear of BP/PVDF composites will be presented. Finally, the future challenges and opportunities in the use of BP materials as lubricants will be discussed.


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Black phosphorus as a new lubricant

Show Author's information Wei WANGGuoxin XIE( )Jianbin LUO( )
State Key Laboratory of Tribology, Tsinghua University, Beijing 100084, China

Abstract

In recent years, a new 2D-layered material—black phosphorus (BP)—has been a rising star after the era of graphene owing to its high charge carrier mobility, tunable direct bandgap and unique in-plane anisotropic structure. With the development of the synthesis and modification methods of BP, its extensive applications, e.g., transistors, batteries and optoelectronics have emerged. In order to explore its full potential, research into the tribological properties of BP 2D-layered materials such as lubrication additives and fillers in self-lubricating composite materials would be not only of high scientific value but also of practical significance. In this work, recent advances on the friction and lubrication properties of BP nanosheets made by our group, including the micro-friction properties, the lubrication properties of BP nanosheets as water-based and oil-based lubrication additives, and the friction and wear of BP/PVDF composites will be presented. Finally, the future challenges and opportunities in the use of BP materials as lubricants will be discussed.

Keywords:

black phosphorus, two-dimensional (2D) material, lubricant additive, self-lubricating composite materials, friction
Received: 20 June 2017 Revised: 18 October 2017 Accepted: 07 December 2017 Published: 07 February 2018 Issue date: March 2018
References(82)
[1]
Dasic P. International standardization and organizations in the field of tribology. Ind Lubr Tribol 55(6):287–291(2003)
[2]
Jost H P. Tribology micro & macroeconomics: A road to economic savings. Tribol Lubr Technol 61(10):18–22(2005)
[3]
Iliuc I. Plenary lecture V: EU objective of 120g CO2/km emission for new cars a challenge for tribology. In Proceedings of the 9th WSEAS International Conference on Mathematics & Computers in Biology & Chemistry, Bucharest, Romania, 2008: 15.
[4]
Xia Y Q, Xu X C, Feng X, Chen G X. Leaf-surface wax of desert plants as a potential lubricant additive. Friction 3(3):208–213(2015)
[5]
Xu J, Li J J. New achievements in superlubricity from international workshop on superlubricity: Fundamental and applications. Friction 3(4):344–351(2015)
[6]
Li J J, Zhang C H, Luo J B. Superlubricity behavior with phosphoric acid-water network induced by rubbing. Langmuir 27(15):9413–9417(2011)
[7]
Novoselov K S, Jiang D, Schedin F, Booth T J, Khotkevich V V, Morozov S V, Geim A K. Two-dimensional atomic crystals. Proc Natl Acad Sci USA 102(30):10451–10453(2005)
[8]
Filleter T, Bennewitz R. Structural and frictional properties of graphene films on SiC(0001) studied by atomic force microscopy. Phys Rev B 81(15):155412(2010)
[9]
Dienwiebel M, Verhoeven G S, Pradeep N, Frenken J W M, Heimberg J A, Zandbergen H W. Superlubricity of graphite. Phys Rev Lett 92(12):126101(2004)
[10]
Chu T, Ilatikhameneh H, Klimeck G, Rahman R, Chen Z H. Electrically tunable bandgaps in bilayer MoS2. Nano Lett 15(12):8000–8007(2015)
[11]
Kumari S, SharamaO P, Gusain R, Mungse H P, Kukrety A, Kumar N, Sugimura H, Khatri O P. Alkyl-chain-grafted hexagonal boron nitride nanoplatelets as oil-dispersible additives for friction and wear reduction. ACS Appl Mater Interfaces 7(6):3708–3716(2015)
[12]
Erdemir A, Eryilmaz O. Achieving superlubricity in DLC films by controlling bulk, surface, and tribochemistry. Friction 2(2):140–155(2014)
[13]
Ataca C, Şahin H, Aktürk E, Ciraci S. Mechanical and electronic properties of MoS2 nanoribbons and their defects. J Phys Chem C 115(10):3934–3941(2011)
[14]
Berman D, Erdemir A, Sumant A V. Few layer graphene to reduce wear and friction on sliding steel surfaces. Carbon 54:454–459(2013)
[15]
Liu D E, Xie G X, Guo D, Cui Z Y, Si L N, Wan C L, Zou W, Luo J B. Tunable lubricity of aliphatic ammonium graphite intercalation compounds at the micro/nanoscale. Carbon 115:574–583(2017)
[16]
Guo W L, Yin J, Qiu H, Guo Y F, Wu H R, Xue M M. Friction of low-dimensional nanomaterial systems. Friction 2(3):209–225(2014)
[17]
Zhang W, Zhou M, Zhu H W, Tian Y, Wang K L, Wei J Q, Ji F, Li X, Li Z, Zhang P, et al. Tribological properties of oleic acid-modified graphene as lubricant oil additives. J Phys DAppl Phys 44(20):205303(2011).
[18]
Wang H D, Liu Y H, Liu W R, Wang R, Wen J G, Sheng H P, Feng J f, Erdemir A, Luo J B.Tribological Behavior of NiAl-Layered Double Hydroxide Nanoplatelets as Oil-Based Lubricant Additives. ACS Appl. Mater. Interfaces 9 (36): 30891–30899 (2017).
[19]
Kogovšek J, Kalin M. Various MoS2-, WS2- and C-based micro-and nanoparticles in boundary lubrication. Tribol Lett 53(3):585–597(2014)
[20]
Chen Z, Liu X W, Liu Y H, GunselS, Luo J B. Ultrathin MoS2 nanosheets with superior extreme pressure property as boundary lubricants. Sci Rep 5:12869(2015)
[21]
Xie G X, Forslund M, Pan J S. Direct electrochemical synthesis of reduced graphene oxide (rGO)/copper composite films and their electrical/electroactive properties. ACS Appl Mater Interfaces 6(10):7444–7455(2014)
[22]
Belmonte M, Ramírez C, González-Julián J, Schneider J, Miranzo P, Osendi M I. The beneficial effect of graphene nanofillers on the tribological performance of ceramics. Carbon 61:431–435(2013)
[23]
Sorrentino A, Altavilla C, Merola M, Senatore A, Ciambelli P, Iannace S. Nanosheets of MoS2-oleylamine as hybrid filler for self-lubricating polymer composites: Thermal, tribological, and mechanical properties. Polym Compos 36(6):1124–1134(2015)
[24]
Ling X, Wang H, Huang S X, Xia F N, Dresselhaus M S. The renaissance of black phosphorus. Proc Natl Acad Sci USA 112(15):4523–4530(2015)
[25]
Tao J, Shen W F, Wu S, Liu L, Feng Z H, Wang C, Hu C G, Yao P, Zhang H, Pang W, et al. Mechanical and electrical anisotropy of few-layer black phosphorus. ACS Nano 9(11):11362–11370(2015)
[26]
Chen H, Huang P, Guo D, Xie G X. Anisotropic mechanical properties of black phosphorus nanoribbons. J Phys Chem C 120(51):29491–29497(2016)
[27]
Liu H, Du Y C, Deng Y X, Ye P D. Semiconducting black phosphorus: Synthesis, transport properties and electronic applications. Chem Soc Rev 44(9):2732–2743(2015)
[28]
Lei W Y, Liu G, Zhang J, Liu M H. Black phosphorus nanostructures: Recent advances in hybridization, doping and functionalization. Chem Soc Rev 46(12):3492–3509(2017)
[29]
Lee T H, Kim S Y, Jang H W. Black phosphorus: Critical review and potential for water splitting photocatalyst. Nanomaterials 6(12):194(2016)
[30]
Castellanos-Gomez A. Black phosphorus: Narrow gap, wide applications. J Phys Chem Lett 6(21):4280–4291(2015)
[31]
Du Y L, Ouyang C Y, Shi S Q, Lei M S. Ab initio studies on atomic and electronic structures of black phosphorus. J Appl Phys 107(9):093718(2010)
[32]
Kim H. Effect of van der Waals interaction on the structural and cohesive properties of black phosphorus. J Korean Phys Soc 64(4):547–553(2014)
[33]
Wang Z H, Feng P X L. Design of black phosphorus 2D nanomechanical resonators by exploiting the intrinsic mechanical anisotropy. 2D Mater 2(2):021001(2015)
[34]
Brent J R, Savjani N, Lewis E A, Haigh S J, Lewis D J, O'Brien P. Production of few-layer phosphorene by liquid exfoliation of black phosphorus. Chem Commun 50(87):13338–13341(2014)
[35]
Bridgman P W. Two new modifications of phosphorus. J Am Chem Soc 36(7):1344–1363(1914)
[36]
Maruyama Y, Suzuki S, Kobayashi K, Tanuma S. Synthesis and some properties of black phosphorus single crystals. Phys BC 105(1–3):99–102(1981)
[37]
Shirotani I. Growth of large single crystals of black phosphorus at high pressures and temperatures, and its electrical properties. Mol Cryst Liq Cryst 86(1):203–211(1982)
[38]
Endo S, Akahama Y, Terada S, Narita S. Growth of large single crystals of black phosphorus under high pressure. Jpn J Appl Phys 21(8):L482–L484(1982)
[39]
Park C M, Sohn H J. Black phosphorus and its composite for lithium rechargeable batteries. Adv Mater 19(18):2465–2468(2007)
[40]
Krebs H, Schultze-Gebhardt F. Über die Struktur und Eigenschaften der Halbmetalle. VII. Neubestimmung der Struktur des glasigen Selens nach verbesserten röntgenographischen Methoden. Acta Crystallogr 8(7):412–419(1955)
[41]
Nilges T, Kersting M, Pfeifer T. A fast low-pressure transport route to large black phosphorus single crystals. J Solid State Chem 181(8):1707–1711(2008)
[42]
Liu H, Neal A T, Zhu Z, Luo Z, Xu X F, Tománek D, Ye P D. Phosphorene: An unexplored 2D semiconductor with a high hole mobility. ACS Nano 8(4):4033–4041(2014)
[43]
Lu W L, Nan H Y, Hong J H, Chen Y M, Zhu C, Liang Z, Ma X Y, Ni Z H, Jin C H, Zhang Z. Plasma-assisted fabrication of monolayer phosphorene and its Raman characterization. Nano Res 7(6):853–859(2014)
[44]
YasaeiP, KumarB, ForoozanT, Wang C H, AsadiM, TuschelD, IndacocheaJ E, KlieR F, Salehi-KhojinA. High-quality black phosphorus atomic layers by liquid-phase exfoliation. Adv Mater 27(11):1887–1892(2015)
[45]
Bagheri S, Mansouri N, Aghaie E. Phosphorene: A new competitor for graphene. Int J Hydrogen Energy 41(7):4085–4095(2016)
[46]
Rodin A S, Carvalho A, Castro Neto A H. Strain-induced gap modification in black phosphorus. Phys Rev Lett 112(17):176801(2014)
[47]
Asahina H, Morita A. Band structure and optical properties of black phosphorus. J Phys C Solid State Phys 17(11):1839–1852(1984)
[48]
Liu B L, Köpf M, Abbas A N, Wang X M, Guo Q S, Jia Y C, Xia F N, Weihrich R, Bachhuber F, Pielnhofer F, Wang H, Dhall R, Cronin S B, Ge M Y, Fang X, Nilges T, Zhou C W. Black arsenic-phosphorus: Layered anisotropic infrared semiconductors with highly tunable compositions and properties. Adv Mater 27:4423–4429(2015).
[49]
Wang Q H, Kalantar-Zadeh K, Kis A, Coleman J N, Strano M S. Electronics and optoelectronics of two-dimensional transition metal dichalcogenides. Nat Nanotechnol 7(11):699–712(2012)
[50]
Lv R T, Robinson J A, Schaak R E, Sun D, Sun Y F, Mallouk T E, Terrones M. Transition metal dichalcogenides and beyond: Synthesis, properties, and applications of single- and few-layer nanosheets. Acc Chem Res 48(1):56–64(2015)
[51]
Xia F N, Wang H, Xiao D, Dubey M, Ramasubramaniam A. Two-dimensional material nanophotonics. Nat Photonics 8(12):899–907(2014)
[52]
Gusmão R, Sofer Z, Pumera M. Black phosphorus rediscovered: From bulk material to monolayers. Angew Chem Int Ed Engl 56(28):8052–8072(2017)
[53]
Jiang J W, Park H S. Mechanical properties of single-layer black phosphorus. J Phys D Appl Phys 47(38):385304(2014)
[54]
Qin G Z, Yan Q B, Qin Z Z, Yue S Y, Hu M, Su G. Anisotropic intrinsic lattice thermal conductivity of phosphorene from first principles. Phys Chem Chem Phys17(7):4854–4858(2015)
[55]
Zhang Y Y, Pei Q X, Jiang J W, Wei N, Zhang Y W. Thermal conductivities of single- and multi-layer phosphorene: A molecular dynamics study. Nanoscale 8(1):483–491(2016)
[56]
Huang Y, Qiao J S, He K, Bliznakov S, Sutter E, Chen X J, Luo D, Meng F K, Su D, Decker J, et al. Interaction of black phosphorus with oxygen and water. Chem Mater 28(22) 8330–8339(2016)
[57]
O'Hare P A G, Lewis B M, Shirotani I. Thermodynamic stability of orthorhombic black phosphorus. Thermochim Acta 129(1):57–62(1988)
[58]
Li L K, Yu Y J, Ye G J, Ge Q Q, Ou X D, Wu H, Feng D L, Chen X H, Zhang Y B. Black phosphorus field-effect transistors. Nat Nanotechnol 9(5):372–377(2014)
[59]
Zhu W N, Yogeesh M N, Yang S X, H. Aldave S H, Kim J S, Sonde S, Tao L, Lu N S, Akinwande D. Flexible black phosphorus ambipolar transistors, circuits and AM demodulator. Nano Lett 15(3):1883–1890(2015)
[60]
Abbas A N, Liu B L, Chen L, Ma Y Q, Cong S, Aroonyadet N, Köpf M, Nilges T, Zhou C W. Black phosphorus gas sensors. ACS Nano 9(5):5618–5624(2015)
[61]
Cho S Y, Lee Y, Koh H J, Jung H, Kim J S, Yoo H W, Kim J H, Jung H T. Superior chemical sensing performance of black phosphorus: Comparison with MoS2 and graphene. Adv Mater 28(32):7020–7028(2016)
[62]
Miao J S, Cai L, Zhang S M, Nah J, Yeom J, Wang C. Air-stable humidity sensor using few-layer black phosphorus. ACS Appl Mater Interfaces 9(11):10019–10026(2017)
[63]
Sun J, Lee H W, Pasta M, Yuan H T, Zheng G Y, Sun Y M, Li Y Z, Cui Y. A phosphorene-graphene hybrid material as a high-capacity anode for sodium-ion batteries. Nat Nanotechnol 10(11):980–985(2015)
[64]
Shen Z R, Sun S T, Wang W J, Liu J W, Liu Z F, Yu J C. A black-red phosphorus heterostructure for efficient visible- light-driven photocatalysis. J Mater Chem A 3(7):3285–3288(2015)
[65]
Sa B S, Li Y L, Qi J S, Ahuja R, Sun Z M. Strain engineering for phosphorene: The potential application as a photocatalyst. J Phys Chem C 118(46):26560–26568(2014)
[66]
Zhang X, Xie H M, Liu Z D, Tan C L, Luo Z M, Li H, Lin J D, Sun L Q, Chen W, Xu Z C, et al. Black phosphorus quantum dots. Angew Chem Int Ed Engl 54(12):3653–3657(2015)
[67]
Moreno-Moreno M, Lopez-Polin G, Castellanos-Gomez A, Gomez-Navarro C, Gomez-Herrero J. Environmental effects in mechanical properties of few-layer black phosphorus. 2D Mater 3(3):031007(2016)
[68]
Jiang J W, Park H S. Mechanical properties of single-layer black phosphorus. J Phys D Appl Phys 47(38):385304(2014)
[69]
Nagao M, Hayashi A, Tatsumisago M. All-solid-state lithium secondary batteries with high capacity using black phosphorus negative electrode. J Power Sources 196(16):6902–6905(2011)
[70]
Sun C X, Wen L, Zeng J F, Wang Y, Sun Q, Deng L J, Zhao C J, Li Z. One-pot solventless preparation of PEGylated black phosphorus nanoparticles for photoacoustic imaging and photothermal therapy of cancer. Biomaterials 91:81–89(2016)
[71]
Castellanos-Gomez A, Vicarelli L, Prada E, Island J O, Narasimha-Acharya K L, Blanter S I, Groenendijk D J, Buscema M, Steele G A, Alvarez J V, et al. Isolation and characterization of few-layer black phosphorus. 2D Mater 1(2):025001(2014)
[72]
Island J O, Steele G A, van der Zant H S J, Castellanos-Gomez A. Environmental instability of few-layer black phosphorus. 2D Mater 2(1):011002(2015)
[73]
Edmonds M T, Tadich A, Carvalho A, Ziletti A, O’Donnell K M, Koenig S P, Coker D F, Özyilmaz B, Castro Neto A H, Fuhrer M S. Creating a stable oxide at the surface of black phosphorus. ACS Appl Mater Interfaces 7(27):14557–14562(2015)
[74]
Late D J. Liquid exfoliation of black phosphorus nanosheets and its application as humidity sensor. Microporous Mesoporous Mater 225:494–503(2016)
[75]
Maslar J E, Hurst W S, Bowers W J Jr, Hendricks J H. In situ Raman spectroscopic investigation of stainless steel hydrothermal corrosion. Corrosion 58(9):739–747(2002)
[76]
Oblonsky L J, Devine T M. A surface enhanced Raman spectroscopic study of the passive films formed in borate buffer on iron, nickel, chromium and stainless steel. Corros Sci 37(1):17–41(1995)
[77]
Maslar J E, Hurst W S, Bowers W J, HendricksJ H, Aquino M I. In Situ Raman spectroscopic investigation of aqueous iron corrosion at elevated temperatures and pressures. J Electrochem Soc 147(7):2532–2542(2000)
[78]
Hu Z S, Hsu S M, Wang P S. Tribochemical reaction of stearic acid on copper surface studied by surface enhanced Raman spectroscopy. Tribol Trans 35(3):417–422(1992)
[79]
Ma H B, Li J, Chen H, Zuo G X, Yu Y, Ren T H, Zhao Y D. XPS and XANES characteristics of tribofilms and thermal films generated by two P- and/or S-containing additives in water-based lubricant. Tribol Int 42(6):940–945(2009)
[80]
Heuer J K, Stubbins J F. An XPS characterization of FeCO3 films from CO2 corrosion. Corros Sci 41(7):1231–1243(1999)
[81]
Kajdas C, Makowska M, Gradkowski M. Tribochemistry of n-hexadecane in different material systems. Lubr Sci 18(4):255–263(2006)
[82]
Kajdas C, Makowska M, Gradkowski M. Influence of temperature on the tribochemical reactions of hexadecane. Lubr Sci 15(4):329–340(2003)
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Publication history

Received: 20 June 2017
Revised: 18 October 2017
Accepted: 07 December 2017
Published: 07 February 2018
Issue date: March 2018

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© The author(s) 2018

Acknowledgements

The authors would like to acknowledge Xudong Chen, Ziyi Cui, Jinjin Li and Dan Guo for some of experiments present in the manuscript and their helpful discussions. The authors also would like to acknowledge the support of the National Natural Science Foundation of China (Grant Nos. 51527901, 51335005, 51475256, and 51605249).

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