AI Chat Paper
Note: Please note that the following content is generated by AMiner AI. SciOpen does not take any responsibility related to this content.
{{lang === 'zh_CN' ? '文章概述' : 'Summary'}}
{{lang === 'en_US' ? '中' : 'Eng'}}
Chat more with AI
Powered by AMiner. Clicking this button will take you away from SciOpen.
Home Journal of Advanced Ceramics Article
PDF (2 MB)
Cite
EndNote(RIS) BibTeX
Collect
Submit Manuscript AI Chat Paper
Show Outline
Outline
Show full outline
Hide outline
Outline
Show full outline
Hide outline
Research Article | Open Access

Facile fabrication of cordierite-based porous ceramics with magnetic properties

Hao LIa, Cuiwei LIa( ), Huaiming JIAa, Guangjin CHENa, Siyuan LIa, Kepi CHENb, Chang-An WANGc, Liang QIAOd
Center of Materials Science and Engineering, School of Mechanical, Electronic and Control Engineering, Beijing Jiaotong University, Beijing 100044, China
School of Energy, Power and Mechanical Engineering, North China Electric Power University, Beijing 102206, China
State Key Laboratory of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University, Beijing 100084, China
College of Materials Science and Engineering, Zhejiang University of Technology, Hangzhou 310014, China
Show Author Information

Graphical Abstract

Abstract

In this paper, cordierite-based porous ceramics with magnetic properties have been firstly in-situ synthesized by using MgO, Al2O3, and SiO2 powders as raw materials and Fe3O4 as a functional additive. Combining with the foam freeze casting method, near net size fabrication (total linear shrinkage < 2.86%) of the magnetic porous materials was realized by adjusting the amount of Fe3O4. The porosity, compressive strength, and saturation magnetization of the prepared materials were 83.9%–87.8%, 1.51–2.65 MPa, and 1.2–5.8 emu/g, respectively. The phase composition and microstructure evolutions during sintering were investigated briefly. The results showed that the synthesis temperature of cordierite was lowered about 100 ℃ due to the addition of Fe3O4. Except for the main phase-cordierite, Mg–Al–Fe spinel and α-Fe2O3 also existed in the final materials. The lattice parameters of the Mg–Al–Fe spinel and the amount of α-Fe2O3 changed obviously with the change in the sintering temperature and Fe3O4 amount, which mainly influenced the magnetic properties of the prepared materials. Thus, a facile fabrication method of the cordierite-based porous ceramics with the magnetic properties has been put forward in this paper.

Keywords

porous cordierite ceramicsphase compositionmicrostructuremagnetic property

References

[1]
Senguttuvan TD, Kalsi HS, Sharda SK, et al. Sintering behavior of alumina rich cordierite porous ceramics. Mater Chem Phys 2001, 67: 146-150.
Crossref Google Scholar
[2]
Du YF, Wen BL, Shu RL, et al. Potassium titanate whiskers on the walls of cordierite honeycomb ceramics for soot catalytic combustion. Ceram Int 2021, 47: 34828-34835.
Crossref Google Scholar
[3]
Mohamed Shamshuddin SZ, Sundar MS, Thimmaraju N, et al. Synthesis, characterization and catalytic activity studies on cordierite honeycomb coated with ZrO2 based solid super acids. Comptes Rendus Chimie 2012, 15: 799–807.
Crossref Google Scholar
[4]
Zhou TQ, Li LD, Cheng J, et al. Preparation of binary washcoat deposited on cordierite substrate for catalytic applications. Ceram Int 2010, 36: 529-534.
Crossref Google Scholar
[5]
Yao Y, Ochiai T, Ishiguro H, et al. Antibacterial performance of a novel photocatalytic-coated cordierite foam for use in air cleaners. Appl Catal B 2011, 106: 592-599.
Crossref Google Scholar
[6]
Liu J, Dong YC, Dong XF, et al. Feasible recycling of industrial waste coal fly ash for preparation of anorthite-cordierite based porous ceramic membrane supports with addition of dolomite. J Eur Ceram Soc 2016, 36: 1059-1071.
Crossref Google Scholar
[7]
Zhang XZ, Fang DR, Lin B, et al. Asymmetric porous cordierite hollow fiber membrane for microfiltration. J Alloys Compd 2009, 487: 631-638.
Crossref Google Scholar
[8]
Parlak TT, Demirkiran AS. Zeolite usage as source of silica to produce cordierite in MgO–Al2O3–SiO2 system. J Adv Ceram 2018, 7: 370-379.
Crossref Google Scholar
[9]
Wang LL, Ma BY, Ren XM, et al. Phase-engineering strategy of ZrO2 for enhancing the mechanical properties of porous cordierite ceramics. Mater Today Commun 2022, 30: 103032.
Crossref Google Scholar
[10]
Li H, Li CW, Wu LH. Porous cordierite ceramics prepared by foam-gelcasting technique: Phase evolution and properties. J Alloys Compd 2019, 791: 690-699.
Crossref Google Scholar
[11]
Vakalova TV, Pogrebenkov VM, Revva IB, et al. Effect of fluorine-containing additive on the synthesis and sintering of compositions from natural raw materials in the “cordierite–mullite” system. Ceram Int 2019, 45: 9695-9703.
Crossref Google Scholar
[12]
Wang WB, Shi ZM, Wang XG, et al. The phase transformation and thermal expansion properties of cordierite ceramics prepared using drift sands to replace pure quartz. Ceram Int 2016, 42: 4477-4485.
Crossref Google Scholar
[13]
Ogiwara T, Noda Y, Shoji K, et al. Solid state synthesis and its characterization of high density cordierite ceramics using fine oxide powders. J Ceram Soc Jpn 2010, 118: 246-249.
Crossref Google Scholar
[14]
Li Y, Cheng XD, Zhang RF, et al. Effect of excess MgO on the properties of cordierite ceramic sintered by solid-state method. Int J Appl Ceram Technol 2015, 12: 443-450.
Crossref Google Scholar
[15]
Guo W, Lu HB, Feng CX. Influence of La2O3 on preparation and performance of porous cordierite from rice husk. J Rare Earths 2010, 28: 614-617.
Crossref Google Scholar
[16]
Senthil Kumar M, Elaya Perumal A, Vijayaram TR. Synthesis, characterization and sintering behavior influencing mechanical, thermal and physical properties of pure cordierite and cordierite-ceria. J Adv Ceram 2015, 4: 22-30.
Crossref Google Scholar
[17]
Ren XM, Ma BY, Zhang YR, et al. Effects of sintering temperature and V2O5 additive on the properties of SiC–Al2O3 ceramic foams. J Alloys Compd 2018, 732: 716-724.
Crossref Google Scholar
[18]
Li Y, Zhao HZ. Effect of Fe2O3 addition on sintering behavior of cordierite ceramic obtained by solid-state sintering method. J Aust Ceram Soc 2019, 55: 567-574.
Crossref Google Scholar
[19]
Lu AH, Schmidt W, Matoussevitch N, et al. Nanoengineering of a magnetically separable hydrogenation catalyst. Angew Chem Int Ed Engl 2004, 43: 4303-4306.
Crossref Google Scholar
[20]
Wang LX, Guan YK, Qiu X, et al. Efficient ferrite/Co/ porous carbon microwave absorbing material based on ferrite@metal-organic framework. Chem Eng J 2017, 326: 945-955.
Crossref Google Scholar
[21]
Yang SD, Chen L, Mu L, et al. Magnetic graphene foam for efficient adsorption of oil and organic solvents. J Colloid Interface Sci 2014, 430: 337-344.
Crossref Google Scholar
[22]
Ling L, Zhang WX. Enrichment and encapsulation of uranium with iron nanoparticle. J Am Chem Soc 2015, 137: 2788-2791.
Crossref Google Scholar
[23]
Borlido L, Azevedo AM, Roque ACA, et al. Magnetic separations in biotechnology. Biotechnol Adv 2013, 31: 1374-1385.
Crossref Google Scholar
[24]
Peretyat’ko PI, Kulikov LA, Melikhov IV, et al. Magnetic porous composite material: Synthesis and properties. Tech Phys Lett 2015, 41: 974-976.
Crossref Google Scholar
[25]
Qi X, Zhou X, Shu D, et al. Effect of porous structure on the magnetic properties of NixMgyZn1–x–yFe2O4 magnetic materials. Chin Phys Lett 2011, 28: 107502.
Crossref Google Scholar
[26]
Wang JN, Novaro O, Li CL. Mössbauer spectroscopy and X-ray diffraction studies of Mg–Al–Fe–O mixed spinel sulphur transfer catalysts. J Mater Sci 1998, 33: 3671-3676.
Crossref Google Scholar
[27]
Lee CC, Yoshikawa N, Taniguchi S. Microwave-induced substitutional-combustion reaction of Fe3O4/Al ceramic matrix porous composite. J Mater Sci 2011, 46: 7004-7011.
Crossref Google Scholar
[28]
Sandeep Kumar TK, Viswanathan NN, Ahmed HM, et al. Estimation of sintering kinetics of magnetite pellet using optical dilatometer. Metall Mater Trans B 2016, 47: 309-319.
Crossref Google Scholar
[29]
Huang YM, Zhai BG, Ma QL, et al. Magnetic properties of ferrous ferric oxide confined in porous silicon. Mater Sci Forum 2010, 663–665: 1142-1145.
Crossref Google Scholar
[30]
Tan P, Jiang Y, Liu XQ, et al. Magnetically responsive porous materials for efficient adsorption and desorption processes. Chin J Chem Eng 2019, 27: 1324-1338.
Crossref Google Scholar
[31]
Wang S. Effects of Fe on crystallization and properties of a new high infrared radiance glass-ceramics. Environ Sci Technol 2010, 44: 4816-4820.
Crossref Google Scholar
[32]
Li H, Li JW, Li CW, et al. Near net shape fabrication of porous cordierite by combination of foam gel-casting and freeze-drying. Int J Appl Ceram Technol 2021, 18: 2121-2131.
Crossref Google Scholar
[33]
Li CW, Han Y, Wu LH, et al. Synthesis and growth of anorthite crystal during in situ preparation of porous anorthite ceramics by foam-gelcasting. Int J Appl Ceram Technol 2017, 14: 957-962.
Crossref Google Scholar
[34]
Wu WQ, Ruan YZ, Yu Y. Influence of Fe2O3 impurity on the crystalline structure of cordierite synthesized from waste aluminum slag. Chinese J Struc Chem 2005, 24: 483-487.
Google Scholar
[35]
Koepke J, Schulz H. Single crystal structure investigations under high-pressure of the mineral cordierite with an improved high-pressure cell. Phys Chem Miner 1986, 13: 165-173.
Crossref Google Scholar
[36]
Cheng JJ. Reaction of Mg–Cr spinel with iron oxide in solid phase. J Chin Ceram Soc 1965, 4: 30-42. (in Chinese)
Google Scholar
[37]
De Vekey RC, Majumdar AJ. Nucleation and crystallization studies of some glasses in the CaO–MgO–Al2O3–SiO2 system. Mineral Mag 1970, 37: 771-779.
Crossref Google Scholar
[38]
Li H, Li CW, Wu LH, et al. Near net size sintering of porous cordierite ceramics with excellent properties. J Alloys Compd 2020, 826: 154121.
Crossref Google Scholar
[39]
Wang SX, Wang H, Chen ZW, et al. Fabrication and characterization of porous cordierite ceramics prepared from fly ash and natural minerals. Ceram Int 2019, 45: 18306-18314.
Crossref Google Scholar
[40]
Li X, Li YB, Xiang RF, et al. Effect of dispersion viscosity on microstructure of cordierite foam prepared by thermo-foaming. Ceram Int 2019, 45: 24487-24492.
Crossref Google Scholar
[41]
Gibson LJ, Ashby MF. Cellular Solids. Cambridge: Cambridge University Press, 1997.
Crossref
[42]
Cao M, Liu T, Gao S, et al. Single-crystal dendritic micro-pines of magnetic α-Fe2O3: Large-scale synthesis, formation mechanism, and properties. Angew Chem Int Ed Engl 2005, 44: 4197–4201.
Crossref Google Scholar
[43]
Krause T, Molotnikov A, Carlesso M, et al. Mechanical properties of topologically interlocked structures with elements produced by freeze gelation of ceramic slurries. Adv Eng Mater 2012, 14: 335-341.
Crossref Google Scholar
[44]
Li H, Li CW, Wu LH, et al. In-situ synthesis and properties of porous cordierite ceramics with adjustable pore structure. Ceram Int 2020, 46: 14808-14815.
Crossref Google Scholar
Journal of Advanced Ceramics
Volume 11 Issue 10,
October 2022
Pages 1583-1595
DOI: 10.1007/s40145-022-0631-1
Cite this article:
LI H, LI C, JIA H, et al. Facile fabrication of cordierite-based porous ceramics with magnetic properties. Journal of Advanced Ceramics, 2022, 11(10): 1583-1595. https://doi.org/10.1007/s40145-022-0631-1

1262

Views

154

Downloads

24

Crossref

24

Web of Science

26

Scopus

0

CSCD

Altmetrics
Received: 28 April 2022
Revised: 21 May 2022
Accepted: 10 July 2022
Published: 02 September 2022
© The Author(s) 2022.

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made.

The images or other third party material in this article are included in the article’s Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder.

To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.
Return