Enhanced energy storage properties of Bi0.5Li0.5TiO3 modified Sr0.1Bi0.45Na0.45TiO3 based ceramics

Qin FENG; Xiao LIU; Changlai YUAN; Xinyu LIU; Changrong ZHOU; Guohua CHEN

doi:10.1007/s40145-016-0193-1

Journal of Advanced Ceramics 2016, 5(3): 219-224 https://doi.org/10.1007/s40145-016-0193-1

Research Article |

Open Access | Issue | Published: 21 August 2016

Enhanced energy storage properties of Bi_0.5Li_0.5TiO₃ modified Sr_0.1Bi_0.45Na_0.45TiO₃ based ceramics

Show Author's Information Hide Author's Information Qin FENG^{^a^,^b}, Xiao LIU^{^c}, Changlai YUAN^{^b}(

), Xinyu LIU^{^a^,^b}, Changrong ZHOU^{^b}, Guohua CHEN^{^b}

^a College of Material Science and Engineering, Central South University, Changsha 410083, China

^b College of Material Science and Engineering, Guilin University of Electronic Technology, Guilin 541004, China

^c College of Powder Metallurgy Research Institute, Central South University, Changsha 410083, China

Keywords:

ferroelectricity, energy storage, Bi_0.5Li_0.5TiO₃

Cite this article:

FENG Q, LIU X, YUAN C, et al. Enhanced energy storage properties of Bi_0.5Li_0.5TiO₃ modified Sr_0.1Bi_0.45Na_0.45TiO₃ based ceramics. Journal of Advanced Ceramics, 2016, 5(3): 219-224. https://doi.org/10.1007/s40145-016-0193-1

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Abstract

Lead-free (1-x)Sr_0.1Bi_0.45Na_0.45TiO₃-xBi_0.5Li_0.5TiO₃ (x = 0-0.4) ceramics were successfully prepared by a solid-state reaction technique. The effects of amount of Bi_0.5Li_0.5TiO₃ on structure and electrical properties were examined. The X-ray diffraction (XRD) analysis revealed that all the investigated specimens have a perovskite structure. An obvious change in microstructure with the increase of Bi_0.5Li_0.5TiO₃ concentration was observed. This study demonstrated that relaxor could be stabilized in Sr_0.1Bi_0.45Na_0.45TiO₃ based ceramics by lowering the tolerance factor and electronegativity difference. Besides, a dielectric anomaly related to thermal evolution of crystallographic symmetry was emerged at the depolarization temperature. Upon incorporation of 26 mol% Bi_0.5Li_0.5TiO₃, the specimens were able to withstand an electric field intensity of 106.9 kV/cm with an energy density of 0.88 J/cm³ and an energy efficiency of 65%.

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Enhanced energy storage properties of Bi_0.5Li_0.5TiO₃ modified Sr_0.1Bi_0.45Na_0.45TiO₃ based ceramics

Show Author's information Hide Author's Information Qin FENG^{^a^,^b}, Xiao LIU^{^c}, Changlai YUAN^{^b}(

), Xinyu LIU^{^a^,^b}, Changrong ZHOU^{^b}, Guohua CHEN^{^b}

^a College of Material Science and Engineering, Central South University, Changsha 410083, China

^b College of Material Science and Engineering, Guilin University of Electronic Technology, Guilin 541004, China

^c College of Powder Metallurgy Research Institute, Central South University, Changsha 410083, China

Abstract

Keywords: ferroelectricity, energy storage, Bi_0.5Li_0.5TiO₃

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Publication history

Received: 03 April 2016

Revised: 24 May 2016

Accepted: 30 May 2016

Published: 21 August 2016

Issue date: September 2016

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Acknowledgements

Financial supports of the National Natural Science Foundation of China (Grant Nos. 11464006, 61561011, and 51462005) and the Natural Science Foundation of Guangxi (Grant No. 2014GXNSFBA118254) are gratefully acknowledged by the authors.

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