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Research Article

Self-supported Ni6MnO8 3D mesoporous nanosheet arrays with ultrahigh lithium storage properties and conversion mechanism by in-situ XAFS

Dongdong Zhao1,§, Peng Yu1,§, Lei Wang1( ), Fanfei Sun2, Li Zhao1, Chungui Tian1, Wei Zhou1, Honggang Fu1( )
Key Laboratory of Functional Inorganic Material Chemistry,Ministry of Education of the People's Republic of China, Heilongjiang University,Harbin,150080,China;
Shanghai Synchrotron Radiation Facility (SSRF),Shanghai Institute of Applied Physics, Chinese Academy of Sciences,Shanghai,201204,China;

§ These authors contributed equally to this work.

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Graphical Abstract

Abstract

Murdochite-type Ni6MnO8 three-dimensional mesoporous nanosheet arrays grown on carbon cloth (NMO-SA/CC) are synthesized using an in-situ growth strategy. As self-supported binder-free anodes for LIBs, the NMO-SA/CC hierarchical nanostructures exhibit ultrahigh capacity, excellent cycling stability, and good rate capability. The excellent lithium storage performance can be ascribed to the perfect electrical contact between NMO-SA and CC. The mesopores in the thin nanosheet can maximize the electrode contact with the electrolyte by decreasing the Li+ diffusion path. Moreover, these effects relieve the pulverization and agglomeration that originate from the large volume variations during the Li+ intercalation/deintercalation cycles. The in-situ X-ray absorption fine structure (XAFS) spectrum recorded during the initial lithiation/delithiation processes reveals the conversion reaction process.

Keywords

Ni6MnO8self-supportedin-situ X-ray absorption fine structurelithium-ion battery

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Nano Research
Volume 10 Issue 1,
January 2017
Pages 263-275
DOI: 10.1007/s12274-016-1285-5
Cite this article:
Zhao D, Yu P, Wang L, et al. Self-supported Ni6MnO8 3D mesoporous nanosheet arrays with ultrahigh lithium storage properties and conversion mechanism by in-situ XAFS. Nano Research, 2017, 10(1): 263-275. https://doi.org/10.1007/s12274-016-1285-5

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Received: 13 July 2016
Revised: 30 August 2016
Accepted: 07 September 2016
Published: 05 November 2016
© Tsinghua University Press and Springer-Verlag Berlin Heidelberg 2016
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