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Research Article

Active-layer evolution and efficiency improvement of (CH3NH3)3Bi2I9-based solar cell on TiO2-deposited ITO substrate

Xinqian Zhang1,2, Gang Wu1( ), Zhuowei Gu1, Bing Guo1, Wenqing Liu1, Shida Yang1, Tao Ye1, Chen Chen1, Weiwei Tu1, Hongzheng Chen1( )
State Key Laboratory of Silicon MaterialsMOE Key Laboratory of Macromolecular Synthesis and FunctionalizationDepartment of Polymer Science and EngineeringZhejiang UniversityHangzhou310027China
Department of Chemical EngineeringXinjiang Agriculture UniversityUrumqi830052China
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Abstract

We systematically investigated the development of film morphology and crystallinity of methyl-ammonium bismuth (III) iodide (MA3Bi2I9) through onestep spin-coating on TiO2-deposited indium tin oxide (ITO)/glass. The precursor solution concentration and substrate structure have been demonstrated to be critically important in the active-layer evolution of the MA3Bi2I9-based solar cell. This work successfully improved the cell efficiency to 0.42% (average: 0.38%) with the mesoscopic architecture of ITO/compact-TiO2/mesoscopic-TiO2 (meso-TiO2)/MA3Bi2I9/2, 2′, 7, 7′-tetrakis(N, N-di-4-methoxyphenylamino)-9, 9′spiro-bifluorene (spiro-MeOTAD)/MoO3/Ag under a precursor concentration of 0.45 M, which provided the probability of further improving the efficiency of the Bi3+-based lead-free organic–inorganic hybrid solar cells.

Keywords

methyl-ammonium bismuth (III) iodideorganic–inorganic hybrid solar cellTiO2-depostied indium tin oxide (ITO) substratemorphology and crystallinityprecursor solution concentration

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Nano Research
Volume 9 Issue 10,
October 2016
Pages 2921-2930
DOI: 10.1007/s12274-016-1177-8
Cite this article:
Zhang X, Wu G, Gu Z, et al. Active-layer evolution and efficiency improvement of (CH3NH3)3Bi2I9-based solar cell on TiO2-deposited ITO substrate. Nano Research, 2016, 9(10): 2921-2930. https://doi.org/10.1007/s12274-016-1177-8

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Received: 12 March 2016
Revised: 09 June 2016
Accepted: 09 June 2016
Published: 18 July 2016
© Tsinghua University Press and Springer-Verlag Berlin Heidelberg 2016
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