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Polyoxometalates 2024, 3(2): 9140047 https://doi.org/10.26599/POM.2023.9140047
Review Article | Open Access | Issue | Published: 04 January 2024

Supramolecular self-assembly of polyoxometalates and cyclodextrin: Progress and perspectives

Show Author's Information Pai Wang1,§,  Zitong Wang1,§,  Peisen Wang1,  Aadil Nabi Chishti1,  Hongxu Zhang1,  Jianhang Shi1,  Lubin Ni1 ( ),  Saba Jamil3 ( ),  Yongge Wei2 ( )
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, China
Key Lab of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, China
Department of Chemistry, University of Agriculture, Faisalabad 38000, Pakistan

§ Pai Wang and Zitong Wang contributed equally to this work.

Keywords:
self-assembly, polyoxometalates, host–guest interaction, cyclodextrins
Cite this article:
Wang P, Wang Z, Wang P, et al. Supramolecular self-assembly of polyoxometalates and cyclodextrin: Progress and perspectives. Polyoxometalates, 2024, 3(2): 9140047. https://doi.org/10.26599/POM.2023.9140047
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Abstract Full text About this article

In this study, we present a comprehensive overview of supramolecular self-assemblies comprising cyclodextrins (CDs) and polyoxometalates (POMs). We summarize the recent advancements in supramolecular POM–CD systems, including their structures, functions, and applications. Subsequently, we focus on the self-assembly behavior of CDs and POMs, encompassing the formation of inclusion complexes, host–guest interactions, and the development of hybrid materials. In addition, we discuss the remarks on future outlooks and hope that this review will serve as a valuable reference for researchers engaged in the fields of supramolecular/POM chemistry, materials science, and nanotechnology.


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About this article

Supramolecular self-assembly of polyoxometalates and cyclodextrin: Progress and perspectives

Show Author's information Pai Wang1,§, Zitong Wang1,§, Peisen Wang1, Aadil Nabi Chishti1, Hongxu Zhang1, Jianhang Shi1, Lubin Ni1 ( ), Saba Jamil3 ( ), Yongge Wei2 ( )
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, China
Key Lab of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, China
Department of Chemistry, University of Agriculture, Faisalabad 38000, Pakistan

§ Pai Wang and Zitong Wang contributed equally to this work.

Abstract

In this study, we present a comprehensive overview of supramolecular self-assemblies comprising cyclodextrins (CDs) and polyoxometalates (POMs). We summarize the recent advancements in supramolecular POM–CD systems, including their structures, functions, and applications. Subsequently, we focus on the self-assembly behavior of CDs and POMs, encompassing the formation of inclusion complexes, host–guest interactions, and the development of hybrid materials. In addition, we discuss the remarks on future outlooks and hope that this review will serve as a valuable reference for researchers engaged in the fields of supramolecular/POM chemistry, materials science, and nanotechnology.

Keywords: self-assembly, polyoxometalates, host–guest interaction, cyclodextrins

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Received: 21 September 2023
Revised: 19 November 2023
Accepted: 26 November 2023
Published: 04 January 2024
Issue date: June 2024

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© The Author(s) 2024. Published by Tsinghua University Press.

Acknowledgements

Acknowledgement

This work was supported by the National Natural Science Foundation of China (Nos. 21971221 and 21401162), the Yangzhou University Interdisciplinary Research Foundation for Chemistry Discipline of Targeted Support (No. yzuxk202010), High-Level Entrepreneurial and Innovative Talents Program of Yangzhou University, “Qing Lan Project” in Colleges and Universities of Jiangsu Province, Innovation and entrepreneurship training programs for college students in Jiangsu (No. 202211117066Z), and Lvyangjinfeng Talent Program of Yangzhou.

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